A manganese(III) porphyrin/rhodium(III) bipyridine/formate catalyst system for the reductive activation of molecular oxygen
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چکیده
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متن کاملTHE ACTIVATION OF CARBON DIOXIDE AT A MAGNESIUM (1 00) SURFACE THE ROLE OF OXYGEN TRANSIENTS
X-ray photoelectron and high resolution electron energy loss spectroscopic (XPS-HREELS) studies have shown that the adsorption of carbon dioxide at Mg(100) surfaces at 80K is followed by a dissociative reaction leading to the formation of a metastable surface carbonate above 80K. The formation of a carbonate species is proposed to proceed through oxidation of C0 (g) by an active oxygen su...
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ژورنال
عنوان ژورنال: Journal of Molecular Catalysis A: Chemical
سال: 1996
ISSN: 1381-1169
DOI: 10.1016/s1381-1169(96)00137-9